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Die Casting Dies
Recent studies from 2006 and continuing into 2008 by various labs
and organizations have found that one of the many causes of soldering is due to
the impingement of aluminum to the die steel which effectively weakens the
steel. This along with temperature, wettability, and metal velocity are
other contributing factors. To make a bad situation even worse, aluminum
(Al) and iron (Fe) have a natural chemical affinity to one another because of
their make up and electron imbalance. When contacting each other, they
want to form intermetallic compounds.
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| Stage |
Description |
Cause |
| I |
Erosion of grain boundaries |
Weak regions - cavitation |
| II |
Pitting of die surface |
Loose grain - cavitation |
| III |
Formation of iron-aluminum compounds |
Chemical - electron imbalance |
| IV |
Formation of pyramid shapes |
Rapid diffusion of iron |
| V |
Adherence of Aluminum |
Cracks in surface at pyramids |
| VI |
Erosion pits |
Cavitation loss of yield strength |
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courtesy - Worcester Polytechnic Institute - Diran Apelian
Loss of the tool's protective surface or lubrication barrier between the die and cast molten metal
allows the
creation of intermetallic compounds that cause a chemical adhesion or soldering of the metal to the die's surface. This is most prevalent when an aluminum component is present in the cast metal alloy which can
also include some zinc alloys. The aluminum
alloy and tool steel iron content have a natural affinity for each other... The
compressive stress topography
increases the effective yield strength of the die steel and because of the
topography compression, the tool is able to retain more lubricant than a polished or flat surface (see below figures).
This maintains the needed barrier to prevent the covalent electron bonding from occurring between the aluminum and
iron.
The uniform topography of the
MetaLL
ifeÒ
appearance also affords more surface area for the lube to adhere to than a flat
one and creates greater heat dissipation at the die's surface without causing
excessive lube build-up on the tool. This increased heat dissipation allows the
tool to run cooler thus extending the tool's life while increasing lube
retention ability. If no topography change is required or if certain die locations receive
inadequate lubrication,
then our -
TherMaLLifeÒ
-
(low temperature
nitro-carburizing) process offers another choice for correcting solder problems.
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